By Janet Howell Clark
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Additional info for The Effect of an Electric Field on the Lines of Lithium and Calcium
11 Mn wires on CuN. Left image: STM image (10 mV, 1 nA) of a CuN island on Cu (100). It has been high-pass-filtered to enhance contrast and the lattice positions of Cu (red dots) and N (blue dots) atoms have been overlaid. 1 nA). 34-nm high bump. 30 nm. 45 nm. Individual atoms in the wire cannot be resolved. Artefacts seen to the upper left of all structures are characteristic of the atomic arrangement of the tip used for manipulation. Reprinted with permission from Ref. 8. 12 Individual pentacene molecules on a single-/double-layer NaCl film on Cu(111).
IMAGING MOLECULAR ORBITALS A molecule that electronically is only weakly coupled to a metallic substrate will retain its discrete energy level structure and allow its frontier orbitals to be imaged. The ability to image individual orbitals is the basis of molecular orbital engineering, which will be discussed later. In this section, we present the prerequisites of orbital imaging in greater detail. As an example, we will use pentacene, which is one of the best-studied organic semiconductors and exhibits a relatively small band gap and a high mobility.